Buffer Solutions

IMPORTANT

Buffer Solutions: Overview

This topic covers concepts, such as, Buffer Solutions, Need of Constant pH Solutions, Simple and Mixed Buffers & Utility of Buffer Solutions etc.

Important Questions on Buffer Solutions

EASY
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Penicillin preparations are stabilised by the addition of sodium _____ as a buffer.

MEDIUM
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Write the uses of buffer solutions.

EASY
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Write the use of buffer solutions in the human body.

EASY
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Write any one use of buffer solutions.

MEDIUM
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What are simple buffers?

MEDIUM
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What is the mixed buffer solution?

EASY
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Which of the following pairs will not constitute a buffer solution?

HARD
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A buffer solution can be prepared by mixing equal volumes of

EASY
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Among the following, the correct statement is

MEDIUM
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What is the concentration of sodium acetate that needs to be added to a 0.01 M solution of acetic acid with equal volumes to give a solution of pH=5.5?

pKa of CH3COOH=4.5

EASY
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Choose the wrong statement from the following:

HARD
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For preparing a buffer solution of pH=9, by mixing ammonium chloride and ammonium hydroxide, the ratio of concentrations of salt and base should be_______ Kb=10-3

HARD
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A student prepares 2 L buffer solution of 0.3 M NaH2PO4 and 0.3 M Na2HPO4. The solution is divided in half between the two compartments (each containing 1 L buffer) of an electrolysis cell, using Pt electrodes. Assume that the only reaction is the electrolysis of water and the electrolysis is carried out for 200 min with a constant current of 0.965 A.

Assume that  pK a H 2 PO 4 = 7.2   [Given log 2.33 = 0.37]

pH at anode is

HARD
IMPORTANT

For next two question please follow the same

A student prepares 2 L buffer solution of 0.3 M NaH2PO4 and 0.3 M Na2HPO4. The solution is divided in half between the two compartments (each containing 1 L buffer) of an electrolysis cell, using Pt electrodes. Assume that the only reaction is the electrolysis of water and the electrolysis is carried out for 200 min with a constant current of 0.965 A.

Assume that  pK a H 2 PO 4 = 7.2   [Given log 2.33 = 0.37]

pH at cathode is

HARD
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100 mL of 0.10 M NH4OH mixed with 100 mL of 0.05 M HCl solution

HARD
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The pH of 100 mL of 0.10 M NaOH mixed with 100 mL 0.10 M CH3COOH solution is

MEDIUM
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Blood is a buffer of H2CO3 and HCO3- with pH of 7.4. What will be the ratio of HCO3- to H2CO3 in blood.

HARD
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The ionisation constant of $\mathrm{NH}_{4}^{+}$ in water is $5.6 \times 10^{-10} \mathrm{at}$ $25^{\circ} \mathrm{C} .$ The rate constant for the reaction of $\mathrm{NH}_{4}^{+}$ and $\mathrm{OH}^{-}$ to form $\mathrm{NH}_{3}$ and $\mathrm{H}_{2} \mathrm{O}$ at $25^{\circ} \mathrm{C}$ is $3.4 \times 10^{10}$ litre

$\mathrm{mol}^{-1} \mathrm{sec}^{-1} .$ If equilibrium constant of water at $25^{\circ} \mathrm{C}$ is $1.8 \times 10^{-16},$ thenThe pH of a mixture of

0.1 M NH4OH and
0.1M NH42SO4 solution is Ka of NH4+ is 5.6×10-10 and log1.78=0.25 

HARD
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A buffer of acetic acid (pKa=4.8) with sodium acetate, when CH3COOH and CH3COONa are present in equivalent amounts, has a pH range of

MEDIUM
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Consider the titration of weak monobasic acid HA using 0.1 M NaOH. If initially 100 mL of 0.1 M HA is taken then find the volume of NaOH (in mL) added so that pH of mixture become equal to 5.

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